Thursday, June 14, 2018

Seawater Yields First Grams of Yellowcake Uranium

For the first time, researchers at Pacific Northwest National Laboratory and LCW Supercritical Technologies have created five grams of yellowcake—a powdered form of uranium used to produce fuel for nuclear power production—using acrylic fibers to extract it from seawater.

"This is a significant milestone," said Gary Gill, a researcher at PNNL, a Department of Energy national laboratory, and the only one with a marine research facility, located in Sequim, Wash. "It indicates that this approach can eventually provide commercially attractive nuclear fuel derived from the oceans—the largest source of uranium on earth."

That's where LCW, a Moscow, Idaho clean energy company comes in. LCW with early support from PNNL through DOE's Office of Nuclear Energy, developed an acrylic fiber which attracts and holds on to dissolved uranium naturally present in ocean water.

"We have chemically modified regular, inexpensive yarn, to convert it into an adsorbent which is selective for uranium, efficient and reusable," said Chien Wai, president of LCW Supercritical Technologies. "PNNL's capabilities in evaluating and testing the material, have been invaluable in moving this technology forward."

Wai is a former University of Idaho professor who, along with colleague Horng-Bin Pan, was involved in earlier DOE-funded research to develop materials in order to increase domestic availability of uranium, which is mostly imported into the U.S. currently.

Wai founded LCW and, with funding from the Small Business Innovation Research program, worked out a new approach to adsorb the uranium onto a molecule or ligand that is chemically bound to the acrylic fiber. The result is a wavy looking polymer adsorbent that can be deployed in a marine environment, is durable and reusable.

The adsorbent material is inexpensive, according to Wai. In fact, he said, even waste yarn can be used to create the polymer fiber. The adsorbent properties of the material are reversible, and the captured uranium is easily released to be processed into yellowcake. An analysis of the technology suggests that it could be competitive with the cost of uranium produced through land-based mining. (...)

"For each test, we put about two pounds of the fiber into the tank for about one month and pumped the seawater through quickly, to mimic conditions in the open ocean" said Gill. "LCW then extracted the uranium from the adsorbent and, from these first three tests, we got about five grams—about what a nickel weighs. It might not sound like much, but it can really add up."

by Susan Bauer, Phys.Org |  Read more:
Image: PNNL