Sunday, July 30, 2023

All About Decaffeinated Coffee (And Tea)

More than 90% of American coffee drinkers choose caffeinated brews, but decaf is a great option for those who want the taste and social connections of drinking coffee without the energy boost of caffeine. Luckily, a serendipitous accident in 1905 swamped a shipment of coffee beans with seawater, washing the caffeine out and prompting the development of modern decaffeination methods.

How is coffee decaffeinated?

Like regular coffee, decaf coffee begins as green, unroasted beans. The hard beans are warmed and soaked in liquid to dissolve and remove the caffeine in one of four ways: using water alone, using a mixture of water and solvents (most commonly methylene chloride or ethyl acetate) applied either directly or indirectly, or using water and “supercritical carbon dioxide.”

All four methods are safe, and once the caffeine is removed (well, at least 97% of it), the beans are washed, steamed, and roasted at temperatures that evaporate all the liquids used in decaffeination.

How much caffeine is in decaf coffee?


Decaffeination removes about 97% or more of the caffeine in coffee beans. A typical cup of decaf coffee has about 2 mg of caffeine, compared to a typical cup of regular coffee, which has about 95 mg of caffeine.

Is decaf coffee bad for you?

Like all coffee, decaffeinated coffee is safe for consumption and can be part of a healthy diet.

The U.S. Food and Drug Administration has set a rigorous standard to ensure that any minute traces of solvents used to decaffeinate coffee are safe. FDA measures these traces in “parts per million.” After decaffeination, coffee can contain no more than 10 parts per million of, for example, methylene chloride -- that’s one one-thousandth of a percent. (...)

How much caffeine is too much?

Regulators and health authorities in the United States and around the world have concluded moderate caffeine intake can be part of healthy diets for most adults -- generally up to 400mg per day, or about 4-5 cups of coffee. Guidelines may vary for people with certain medical conditions.

by National C0ffee Association |  Read more:
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[ed. See also: How Is Coffee Decaffeinated? (Britannica). And, since my late night tea prompted this inquiry: How Is Tea Decaffeinated? (Premium Teas). From the history link above: (Live Science):]

"The first commercially successful decaffeination method was invented around 1905, by German coffee merchant Ludwig Roselius. According to Atlas Obscura, one bit of lore about the origins of decaf claims that Roselius received a shipment of coffee beans that was soaked in seawater. Instead of tossing the beans, Roselius decided to process and test them. He found that the coffee had been stripped of its caffeine content but still basically tasted like coffee, albeit a bit salty.

Roselius then figured out he could use benzene — a chemical that, at the time, was also used in paint strippers and aftershave — as a solvent to remove caffeine from coffee beans. His company, Kaffee HAG, was the first to produce instant decaf coffee. The coffee was sold as "Sanka" in the United States by General Foods, and was a mid-20th-century staple — and occasional punchline. (In the 1982 movie "Fast Times at Ridgemont High," a biology teacher pleads with his students, "I'm a little slow today. I just switched to Sanka, so have a heart.")

Benzene is no longer used for decaffeinating coffee because it's a known carcinogen. Instead, companies that use chemical solvents have switched to other substances, predominantly ethyl acetate and methylene chloride, although there has been some controversy about the latter because exposure to high amounts of the substance can be toxic and lead to damage of the central nervous system. The FDA has ruled that miniscule trace amounts of methylene chloride in decaf coffee are not cause for concern, and residues of more than 0.001% are prohibited.

Another method for decaffeinating coffee also originated, somewhat accidentally, in Germany. Chemist Kurt Zosel was working with supercritical carbon dioxide at the Max Planck Institute for Coal Research in Ruhr. Zosel discovered that when the gas is heated and put under a lot of pressure, it enters a supercritical state that can be useful for separating different chemical substances — including separating caffeine from coffee when it's pumped through the beans.

The chemist patented his decaffeination method in 1970; it's still widely used today. According to NPR, crude caffeine can be salvaged during the supercritical carbon dioxide decaffeination process, which is used in sodas, energy drinks and other products.

Yet another method, dubbed the Swiss Water Process, was first used commercially in the 1970s. Kastle explained that first, a batch of green coffee beans is soaked in water. That water becomes saturated with all the soluble components found in coffee — including chlorogenic acid, amino acids and sucrose; the caffeine is then filtered out with carbon. This uncaffeinated liquid, called green coffee extract, is then added to columns of new, rehydrated, green coffee beans that still have their caffeine. Kastle said that caffeine migrates from the beans to the green coffee extract as the beans and liquid seek equilibrium, until the beans are almost entirely caffeine-free."